C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. Stress corrosion cracking of type aisi 304 stainless steel at. This section of fabricator training will deal primarily with the austenitic grades of stainless steels commonly designated the. Also on our website is an introduction handbook called stainless steel primer that explains the various types of stainless steels and some of their properties. The austenitic class contains the most formable, weldable, and corrosionresistant stainless steel grades, but they cannot be heat treated.
Stainless steels are ironbase alloys containing 10. The nickel free 22% chromium cr plus copper, low molybdenum alloy has an overall chloride resistance that is the same if not better than that shown by type 304 stainless steel. Chlorideinduced stresscorrosion cracking scc is one of the failure modes of stainless steels. It has also been used in vacuum processing equipment and specialized instruments where high integrity is essential.
The specialty steel industry of north america ssina and the individual companies it represents have made every effort to ensure that the information presented in this website is technically correct. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Stress corrosion cracking facts and how to reduce the. This is an austenitic chromiumnickel alloy which practically means that it has a very high corrosion resistance. In addition, many paints and insulating coatings contain chlorides, so be sure to choose your insulation carefully for stainless steel pipes. Stress corrosion cracking of type 304 austenitic stainless. Chloride induced stress corrosion cracking of type 304 and. The influence of chloride concentration and acidity on the occurrence of stress corrosion cracking s. Library ssina specialty steel industry of north america. Chlorideinduced transgranular stress corrosion cracking of. Chloride stress corrosion cracking and 316 stainless steel. For more information, please check 304 vs 316 stainless steel. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially.
Chloride stress corrosion cracking in austenitic stainless steel. Chloride induced stress corrosion cracking scc is one of the failure modes of stainless steels. Chloride induced stress corrosion cracking of type 304. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
This mode of attack is termed stress corrosion cracking scc. However, it can be successful in warm chloride environments where exposure is intermittent and cleaning is a regular event such as saucepans and some yacht fittings. Grade 304 is the most commonly used stainless steel. Chloride stress corrosion cracking in austenitic stainless. Type 304 has good processability, weldability, corrosion resistance, heat resistance, low. Transgranular stress corrosion cracking of 304l stainless. Prior cold deformation of the structure under load increases the risk of stress corrosion cracking. Aisi 304 grade stainless steel uns s30400 aisi 304 stainless steel uns s30400 is the most commonly used material in stainless steels, and is usually purchased in an annealed or cold worked state. Alloy 317l austenitic stainless steel plate sandmeyer steel. Influence of high temperature on corrosion behavior of 304 stainless. Effect of temperature on chloride scc of types 304 and 316 stainless. Type 304 is the most widely used alloy of all stainless steels. The datasheet and specification are summarized in the following tables including.
Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Pitting corrosion evaluation of austenitic stainless steel type 304 in acid chloride media r. Stress corrosion cracking facts and how to reduce the risk. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media. Core 3044301 is prone to chlorideinduced stress corrosion cracking at temperatures over about 50 c depending on the applied stress and the chloride concentration in the environment. Pdf chloride induced stress corrosion cracking of type 304 and. Stress corrosion cracking of type aisi 304 stainless steel. Their chemical composition, mechanical properties, weldability and corrosionoxidation. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions. It may be used in either the annealed, cold formed or aswelded condition in many applications where other stainless steel alloys such as type 304, type 410, type 409 and type 430are used. The ferritic class contains moderately formable and corrosion resistant grades compared to other stainless steel classes, but they cannot be heat treated. Stainless steel, due to its superior corrosion resistance relative to most other metals, such as carbon steel and aluminum, becomes the cathode, accelerating the corrosion of the anodic metal. Type 439 stainless steel is a ferritic stainless steel designed to resist corrosion in a variety of oxidizing environments from fresh water to boiling acids.
The chloride stresscorrosion cracking behavior of stainless. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Corrosion of stainless steel in sodium chloride brine solutions. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The saeansi 304 aisi 304 is the most commonly available and used type of stainless steel. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.
How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. The generalpurpose grade, widely used where good formability and corrosion resistance are required. Alloy 317l uns s31703 is a lowcarbon corrosion resistant austenitic chromiumnickelmolybdenum stainless steel. Pdf stress corrosion cracking of austenitic stainless. Stress corrosion cracking scc of austenitic stainless steels has been a known failure. Ss304 grade aisi 304 stainless steel properties, composition. Chloride stress corrosion cracking methods of minimizing. Mar 14, 2012 chloride corrosion induced stress cracking is more likely to occur in temperatures that promote evaporation 100 to 200f due to higher chloride deposits and moisture levels. It is an austenitic, corrosion resistant steel with excellent strength, toughness, fabrication characteristics and weldability. Chloride stress corrosion cracking cscc is a type of intergranular corrosion.
There is an additional risk of stress corrosion cracking scc at higher temperatures. The stress may be applied, as in a pressure system, or it may be residual arising from cold working operations or welding. Stress corrosion cracking stress corrosion cracking is a rapid and severe form of stainless steel corrosion. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries.
It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. It forms when the material is subjected to tensile stress and some kinds of corrosive environments, especially chloriderich environments sea water at higher temperatures. The accepted view is that crevice corrosion is rare below. Types 304 and 304l are the most versatile and widely used of all the stainless steels.
Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless steel is a non magnetic alloy consisting of iron. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. All three families of the highperformance stainless steels will deliver a wide range of resistance to chloride pitting and stress corrosion cracking superior to that of types 304 and 316. Chloride stress corrosion cracking scc of type 304 and 304l austenitic. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. Three general classifications are used to identify stainless steels.
The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Ak steel chromeshield 22 stainless steel exhibits superior chloride pitting resistance when compared to type 430 and type 441 stainless steels. Loto department of chemical and metallurgical engineering, tshwane university of technology, pretoria, south africa received dec 2012, revised 1 feb 20, accepted 1 feb 20 email address. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0. Stress corrosion cracking of sensitized type 304 stainless.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to. Stress corrosion cracking scc can occur in austenitic stainless steels when they are stressed in tension in chloride environments at temperatures in excess of about 60c. Duplex grades are heat treatable and roughly twice as strong as austenitic grades. Chloride stress corrosion cracking stainless steel the three conditions that must be present for chloride stress corrosion to occur are as follows. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloride stress corrosion cracking inspectioneering. The high levels of these elements assure the alloy has superior chloride pitting and general corrosion resistance to the conventional 304304l and 316316l grades. The low carbon version, 304l, may be required for full corrosion resistance when thicker sections are welded.
Design guidelines for the selection and use of stainless steel nidl distributed by. Reference is often made to stainless steel in the singular sense as if it were one material. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. This section of fabricator training will deal primarily with the austenitic grades of stainless steels commonly designated the 300 series 303, 304, 316, 317, 347 etc. Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to scc compared with s30400 and s31600 steels. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. High performance stainless steels nickel institute. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. It forms when the material is subjected to tensile stress and some kinds of corrosive environments, especially chloride rich environments sea water at higher temperatures. The international stainless steel forum issf, of which ssina is a member, is a. However, figure 2b shows some pitting areas the white color areas that. The duplex class offers high resistance to pitting and chloride stress corrosion cracking. In warm chloride environments, 304 is subject to pitting and crevice corrosion and to stress corrosion cracking when subjected to tensile stresses beyond about 50 o c.
Corrosion of stainless steels in supply drinking and. Stress corrosion cracking scc occurs when a susceptible materials under tensile. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Ferritic stainless steels are fecrc alloys with ferrite stabilizers such as aluminum al, columbium cb, molybdenum mo, and titanium ti. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. These technologies use corrosion resistant stainless steels for the production. Pitting corrosion evaluation of austenitic stainless steel. Higher temperatures reduce the permissible chloride level. Stress corrosion cracking has been causing problems in syngas plants since they were first. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i.
Localised corrosion and atmospheric corrosion of stainless steels. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Stress corrosion cracking in a brewery paul mueller company. Although no stainless steel grade is totally immune. Effects of marine environments on stress corrosion cracking of. Ferritic stainless steel an overview sciencedirect topics. Effect of chloride concentration on the scc of solution annealed aisi 304 stainless.
Chromeshield 22 stainless steel resists staining from common food products and has comparable resistance to various cleaners and bleaching agents as type 304. Aisi 304l is the low carbon version of 304 stainless steel, aisi 316 is better than grade 304 in certain properties, corrosion resistance and heat resistance, etc. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. It is also referred to as 188 stainless steel, a2 stainless steel as per the iso 3506, or 304s15 as per the british standard. Stress corrosion cracking international institute of. The effects of coldrolling 20% thickness reduction and sensitization treatment 600c10h on the microstructure, tensile properties and susceptibility to stress corrosion cracking of 304. The austenitic class contains the most formable, weldable, and corrosion resistant stainless steel grades, but they cannot be heat treated. The ferritic class contains moderately formable and corrosionresistant grades compared to other stainless steel classes, but they cannot be. Three underlying factors must be present to cause scc. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Because ss 304 contains 18% chromium cr and 8% nickel ni, its also known as 188 stainless steel. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and.
Chloride stress corrosion involves selective attack of a metal along its grain boundaries. There is an additional risk of stress corrosion cracking scc at. Stress corrosion cracking of austenitic stainless steels in chloride. Pitting or crevice corrosion can occur on most stainless steel grades. The scc propensity of austenitic stainless steels in marine environments is.
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